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题名

A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation

作者
通讯作者Yan,Beibei
发表日期
2023-05-15
DOI
发表期刊
ISSN
0043-1354
EISSN
1879-2448
卷号235
摘要
At present, numerous heterogeneous catalysts have been synthesized to activate persulfate (PS) and produce various reactive species for antibiotic degradation from water. However, the systematic summary of the correlation among catalyst active sites, PS activation pathway and pollutant degradation has not been reported. This review summarized the effect of metal-based, carbon-based and metal-carbon composite catalysts on the degradation of antibiotics by activating PS. Metal and non-metal sites are conducive to inducing different oxidation pathways (SO, OH radical oxidation and O oxidation, mediated electron transfer, surface-bound reactive complexes and high-valent metal oxidation). SO and OH are easy to attack C[sbnd]H, S-N, C[sbnd]N bonds, C[dbnd]C double bonds and amino groups in antibiotics. O is more selective to the structure of the aniline ring and amino group, and also to attacking C[sbnd]S, C[sbnd]N and C[sbnd]H bonds. Surface-bound active species can cleave C[dbnd]C, S[sbnd]N, C[sbnd]S and C[sbnd]N bonds. Other non-radical pathways may also induce different antibiotic degradation routes due to differences in oxidation potential and electronic properties. This critical review clarified the functions of active sites in producing different reactive species for selective oxidation of antibiotics via featured pathways. The outcomes will provide valuable guidance of oriented-regulation of active sites in heterogeneous catalysts to produce on-demand reactive species toward high-efficiency removing antibiotics from water.
关键词
相关链接[Scopus记录]
收录类别
SCI ; EI
语种
英语
重要成果
NI期刊 ; ESI热点 ; ESI高被引
学校署名
其他
资助项目
Tianjin Science and Technology Program[21JCQNJC00400];National Natural Science Foundation of China[52100156];
WOS研究方向
Engineering ; Environmental Sciences & Ecology ; Water Resources
WOS类目
Engineering, Environmental ; Environmental Sciences ; Water Resources
WOS记录号
WOS:000973289500001
出版者
EI入藏号
20231413833261
EI主题词
Aniline ; Carbon carbon composites ; Catalyst activity ; Chemical activation ; Electronic properties ; Free radical reactions ; Free radicals ; Oxidation
EI分类号
Structural Materials Other Than Metal, Plastics or Wood:415.4 ; Medicine and Pharmacology:461.6 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1
ESI学科分类
ENVIRONMENT/ECOLOGY
Scopus记录号
2-s2.0-85151311539
来源库
Scopus
引用统计
被引频次[WOS]:70
成果类型期刊论文
条目标识符//www.snoollab.com/handle/2SGJ60CL/524135
专题工学院_环境科学与工程学院
作者单位
1.School of Environmental Science and Engineering,Tianjin University/Tianjin Key Lab of Biomass/Wastes Utilization,Tianjin,300072,China
2.Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle,Nanchang Hangkong University,Nanchang,330063,China
3.School of Environmental Science & Engineering,Southern University of Science and Technology,Shenzhen,518055,China
4.School of Mechanical Engineering,Tianjin University of Commerce,Tianjin,300134,China
5.School of Chemical Engineering and Advanced Materials,The University of Adelaide,Adelaide,5005,Australia
推荐引用方式
GB/T 7714
Li,Ning,Ye,Jingya,Dai,Haoxi,et al. A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation[J]. Water Research,2023,235.
APA
Li,Ning.,Ye,Jingya.,Dai,Haoxi.,Shao,Penghui.,Liang,Lan.,...&Duan,Xiaoguang.(2023).A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation.Water Research,235.
MLA
Li,Ning,et al."A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation".Water Research 235(2023).
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