题名 | A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation |
作者 | |
通讯作者 | Yan,Beibei |
发表日期 | 2023-05-15
|
DOI | |
发表期刊 | |
ISSN | 0043-1354
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EISSN | 1879-2448
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卷号 | 235 |
摘要 | At present, numerous heterogeneous catalysts have been synthesized to activate persulfate (PS) and produce various reactive species for antibiotic degradation from water. However, the systematic summary of the correlation among catalyst active sites, PS activation pathway and pollutant degradation has not been reported. This review summarized the effect of metal-based, carbon-based and metal-carbon composite catalysts on the degradation of antibiotics by activating PS. Metal and non-metal sites are conducive to inducing different oxidation pathways (SO, OH radical oxidation and O oxidation, mediated electron transfer, surface-bound reactive complexes and high-valent metal oxidation). SO and OH are easy to attack C[sbnd]H, S-N, C[sbnd]N bonds, C[dbnd]C double bonds and amino groups in antibiotics. O is more selective to the structure of the aniline ring and amino group, and also to attacking C[sbnd]S, C[sbnd]N and C[sbnd]H bonds. Surface-bound active species can cleave C[dbnd]C, S[sbnd]N, C[sbnd]S and C[sbnd]N bonds. Other non-radical pathways may also induce different antibiotic degradation routes due to differences in oxidation potential and electronic properties. This critical review clarified the functions of active sites in producing different reactive species for selective oxidation of antibiotics via featured pathways. The outcomes will provide valuable guidance of oriented-regulation of active sites in heterogeneous catalysts to produce on-demand reactive species toward high-efficiency removing antibiotics from water. |
关键词 | |
相关链接 | [Scopus记录] |
收录类别 | |
语种 | 英语
|
重要成果 | NI期刊
; ESI热点
; ESI高被引
|
学校署名 | 其他
|
资助项目 | Tianjin Science and Technology Program[21JCQNJC00400];National Natural Science Foundation of China[52100156];
|
WOS研究方向 | Engineering
; Environmental Sciences & Ecology
; Water Resources
|
WOS类目 | Engineering, Environmental
; Environmental Sciences
; Water Resources
|
WOS记录号 | WOS:000973289500001
|
出版者 | |
EI入藏号 | 20231413833261
|
EI主题词 | Aniline
; Carbon carbon composites
; Catalyst activity
; Chemical activation
; Electronic properties
; Free radical reactions
; Free radicals
; Oxidation
|
EI分类号 | Structural Materials Other Than Metal, Plastics or Wood:415.4
; Medicine and Pharmacology:461.6
; Chemical Reactions:802.2
; Chemical Agents and Basic Industrial Chemicals:803
; Chemical Products Generally:804
; Organic Compounds:804.1
|
ESI学科分类 | ENVIRONMENT/ECOLOGY
|
Scopus记录号 | 2-s2.0-85151311539
|
来源库 | Scopus
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引用统计 |
被引频次[WOS]:70
|
成果类型 | 期刊论文 |
条目标识符 | //www.snoollab.com/handle/2SGJ60CL/524135 |
专题 | 工学院_环境科学与工程学院 |
作者单位 | 1.School of Environmental Science and Engineering,Tianjin University/Tianjin Key Lab of Biomass/Wastes Utilization,Tianjin,300072,China 2.Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle,Nanchang Hangkong University,Nanchang,330063,China 3.School of Environmental Science & Engineering,Southern University of Science and Technology,Shenzhen,518055,China 4.School of Mechanical Engineering,Tianjin University of Commerce,Tianjin,300134,China 5.School of Chemical Engineering and Advanced Materials,The University of Adelaide,Adelaide,5005,Australia |
推荐引用方式 GB/T 7714 |
Li,Ning,Ye,Jingya,Dai,Haoxi,et al. A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation[J]. Water Research,2023,235.
|
APA |
Li,Ning.,Ye,Jingya.,Dai,Haoxi.,Shao,Penghui.,Liang,Lan.,...&Duan,Xiaoguang.(2023).A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation.Water Research,235.
|
MLA |
Li,Ning,et al."A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation".Water Research 235(2023).
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条目包含的文件 | 条目无相关文件。 |
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